Search results for "Emission spectroscopy"
showing 10 items of 180 documents
Spectroscopic study of ion temperature in minimum-B ECRIS plasma
2019
Experimentally determined ion temperatures of different charge states and elements in minimum-B confined electron cyclotron resonance ion source (ECRIS) plasma are reported. It is demonstrated with optical emission spectroscopy, complemented by the energy spread measurements of the extracted ion beams, that the ion temperature in the JYFL 14 GHz ECRIS is 5–28 eV depending on the plasma species and charge state. The reported ion temperatures are an order of magnitude higher than previously deduced from indirect diagnostics and used in simulations, but agree with those reported for a quadrupole mirror fusion experiment. The diagnostics setup and data interpretation are discussed in detail to …
Compact setup for spin-, time-, and angle-resolved photoemission spectroscopy.
2020
Review of scientific instruments 91(6), 063001 (2020). doi:10.1063/5.0004861
Ultrasonic nebulization inductively coupled plasma optical emission spectrometry method for wine analysis
2020
Abstract A methodology was developed to determine mineral elements in wines using Inductively Coupled Plasma Optical Emission Spectrometry combined with ultrasonic nebulization. The concentration of 36 elements (Al, B, Ba, Bi, Ca, Cd, Ce, Co, Cr, Dy, Er, Eu, Fe, Gd, K, La, Lu, Mg, Mn, Mo, Na, Nd, Ni, Pb, Pr, Sb, Sc, Sm, Sr, Tb, Ti, Tm, V, Y, Yb, and Zn) was determined in 59 wine samples and used to distinguish between Brazilian and Spanish wines. The best conditions for the plasma were selected using a two-level factorial design: radiofrequency power 1500 W; plasma gas flow rate 15 L min−1; auxiliary 0.70 L min−1; and nebulizer 0.40 L min−1. An exploratory multivariate analysis by Principal…
II) Wood pellets for home heating can be considered environmentally friendly fuels? Heavy metals determination by inductively coupled plasma-optical …
2016
Abstract The aim of the present study was to determine the concentrations of twelve potentially hazardous elements in wood pellet ashes obtained by the combustion of 13 pellet brands for sale in Italy, the impact of adding the ashes to soils and health risk of operator due to dust exposure. Samples were analysed by Inductively Coupled Plasma Optical Emission Spectrometry. The concentrations of heavy metals in ashes from stoves ranged from 0.41 to 7.2 mg kg − 1 for As, from 1.3 to 12 mg kg − 1 for Sb, from 1.8 to 12 mg kg − 1 for Zn, from 0.23 to 0.8 mg kg − 1 for Pb, from 0.18 to 2.8 mg kg − 1 for Ni, from 0.09 to 1.0 mg kg − 1 for Cd, from 0.46 to 3.4 mg kg − 1 for Cr, from 0.94 to 2.7 mg …
A comparative study on sample preparation procedures for supplementary foods by ICP-OES: Green chemistry considerations
2015
An inductively coupled plasma optical emission (ICP-OES) method was developed for the simultaneous determination of major, minor and trace elements in food. Preliminary studies focused on selecting suitable operational conditions in order to provide the highest sensitivity and to maximize the number of analytes to be determined without spectral or matrix interference. Ruthenium and rhenium were evaluated as internal standards and samples were analyzed at different dilution levels. Furthermore, a comparative study was carried out by using three sample digestion methods, microwave-assisted digestion with HNO3/H2O2, dry ashing and dry ashing with Mg(NO3)2/MgO as an ashing aid. Adequate precisi…
Trace elemental composition of curry by inductively coupled plasma optical emission spectrometry (ICP-OES)
2008
A methodology based on inductively coupled plasma optical emission spectrometry (ICP-OES) after microwave-assisted acid digestion was developed to determine the content of traces elements in curry samples from the Spanish market. The methodology was validated in terms of accuracy by the analysis of citrus and tomato leaf reference materials achieving comparable results with the certified values. The trace metal content of curry samples was compared with data available from previously published reports concerning Indian samples, especially in terms of heavy metal composition, in order to guarantee the quality of the commercially available spices in the European countries. Values found for th…
Optimization of operating conditions of axially and radially viewed plasmas for the determination of trace element concentrations from ultrasound-ass…
2006
Abstract The method of ultrasound-assisted extraction followed by inductively coupled plasma optical emission spectrometry (ICP-OES) used for the determination of trace element concentrations (arsenic, copper, lead, antimony, and zinc) in shooting range areas was optimized. Optimization was achieved not only on the basis of the analysis of appropriate standard reference materials but also on that of 31 synthetic mixtures of matrix and analyte elements (aluminum, antimony, arsenic, calcium, copper, lead, iron, manganese, silicon, and zinc), in five concentrations. All the measurements were performed in robust plasma conditions which were tested by measuring the Mg II 280.270 nm/Mg I 285.213 …
Local Berry curvature signatures in dichroic angle-resolved photoelectron spectroscopy from two-dimensional materials
2020
Orbital polarization and Berry curvature signatures are mapped out by circular dichroism in angle-resolved photoemission.
The determination of antimony and arsenic concentrations in fly ash by hydride generation inductively coupled plasma optical emission spectrometry
2011
Abstract Hydride generation inductively coupled plasma optical emission spectrometry (HG-ICP-OES) was used in the determination of As and Sb concentrations in fly ash samples. The effect of sample pre-treatment reagents and measurement parameters used for hydride generation was evaluated. Due to memory effects observed, the appropriate read delay time was adjusted to 60 s resulting in RSDs 0.6% and 2.3% for As and Sb, respectively. The most suitable volumes of pre-reduction reagents for 10 mL of sample were 4 mL of KI/ascorbic acid (5%) and 6 mL of HCl (conc.). The determination of Sb was significantly interfered by HF, but the interference could be eliminated by adding 2 mL of saturated bo…
Biological mineral content in Iberian skeletal cremains for control of diagenetic factors employing multivariate statistics
2013
Abstract The aim of this study was to define a strategy for a correct selection of bone samples by employing inductively coupled plasma optical emission spectroscopy (ICP-OES) for reconstructing the biological mineral content in bones through the determination of major elements, trace elements and Rare Earth Elements (REE, lanthanides) in skeletal cremains of ancient Iberians (III–II B.C), discovered in the Necropolis of Corral de Saus (Moixent, Valencia) between 1972 and 1979. The biological mineral content was determined taking into account diagenetic factors. A control method for a better reading of results was applied. To explore large geochemical datasets and to reduce the number of va…